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Home My WebLink AboutQuality Contol DocumentationQuality Control Documentation 07030504 Page 24 3/15/2007 1 t01:23 AM r2� � � � AN Quality Control Report ATC Associates, Inc. Vail Analysis: Diesel Range Organics Method: CO DRO Method Blank RunID: HP –V 070311A3715871 Units: mg/kg Analysis Date: 03/11/2007 20:34 Analyst: NW Preparation Date: 03110/2007 15:31 Prep By: JDM Method SW3550B ___ Analyte Result Qua] Rep Limit MDL Diesel Range Organics. C11- C28 _ Surr. n- Pentaoosane ____ —� _ ND � 91.1 _ �v 15 W -0.89 20_154. 0 HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660.0901 WorkOrder: 07030504 Lab Batch ID: 65437 Samples in Analytical Batch: Lab Sample ID Client Sample ID 07030504 -OIA EXC -1 -10' 07030504 -02A EXC -1 -20' 07030504 -03A EXC -1 -25' 07030504 -04A EXC -2 -10' 07030504 -05A EXC -2 -20' 07030504 -06A EXC-2 -25' 07030504 -07A EXC -3 -10' Laboratory Control Sample (LCS) RunID: HP_V_070311A- 3715872 Units: mg/kg Analysis Date: 03/11/2007 20:57 Analyst: NW Preparation Date: 0311012007 15:31 Prep By: JDM Method SW3550B Analyte Diesel Range Organics, C11- C28 Spike Added 66.6 Result 54.2 Percent Recovery 81.3 Qual Lower Limit Upper Limit 50 150 Matrix Spike (MS) / Matrix Spike Duplicate (MSD) Sample Spiked: 07030504 -01 RunID: HP_V 070311A- 3715874 Units: mg/kg -dry Analysis Date: 03/11/2007 21:43 Analyst: NW Preparation Date: 03/10/2007 15:31 Prep By: JDM Method SW3550B Analyte Sample Smp MS MS MS % MS MSD MSD MSD % MSD RPD RPD RPD Low High Result Qual Spike Result Rcvry Qual Spike Result Rcvry Quaf Qua] Limit Limit Limit Added Added 'Diesel Range Organics, C11- C28 1.18 J 68.5 59.1 84.6 68.5 65.6 94.1 10.5 50 50 150 Qualifiers: ND /U - Not Detected at the Method Detection Limit MI - Matrix Interference E - Estimated Value exceeds calibration curve D - Recovery Unreportable due to Dilution J - Estimated value between MDL and PQL ' - Recovery Outside Advisable QC Limits B - Analyte detected in the associated Method Blank N/C - Not Calculated - Sample concentration Is greater than 4 times the amount of spike added. Control limits do not apply. TNTC - Too numerous to count 07030504 Page 25 QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values 311512007 11:01:26 AM calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules. O Quality Control Report ATC Associates, Inc. Vail Analysis: Volatile Organics by Method 8260B Method: SW8260B Method Blank RunID: MSDVOA2_070313A- 3718742 Units: ug/kg Analysis Date: 03113/200711:19 Analyst: DY Preparation Date: 03/13/200711:19 Prep By: Method Analyte Result Qua[ Rep Limit MDL Benzene Eth benzene ND ND 07030504 -01A 5.0 5.0 0.1 0.14 ___ Gasoline Range Organics ND EXC -1 -25' 50 9.7 Toluene ND 07030504 -06A 50 0.17 XOlenes Total ND Xylenes,Total 5.0 0.16 Surr.12- Dichloroethane -d4 92.1 130 41 -155 0 Surr.4- Bromofluombenzene 96.8 Ethylbenzene 64 -147 0 Surr. Toluene -d8 1 102.2 109 52 -152 0 HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660 -0901 Laboratory Control Sample (LCS) RunID: MSDVOA2_070313A -37187 Units: ug/kg Analysis Date: 03/1312007 10:35 Analyst: DY Analyte WorkOrder: 07030504 Result Lab Batch ID: R194829 Samples In Analytical Batch: Lab Sam pie ID Client Sample ID 07030504 -01A EXC -1 -10' 07030504 -02A EXC -1 -20' 07030504 -03A EXC -1 -25' 07030504 -04A EXC -2 -10' 07030504 -05A EXC -2 -20' 07030504 -06A EXC -2 -25' 07030504 -07A EXC -3 -10' Laboratory Control Sample (LCS) RunID: MSDVOA2_070313A -37187 Units: ug/kg Analysis Date: 03/1312007 10:35 Analyst: DY Analyte Spike Added Result Percent Qua[ Recovery -___ _...--- .._------- --- 100 Lower Limit _.._..__._._._.. 70 Upper Limit _. -- 130 Benzene 20.0 20.1 Ethylbenzene Gasoline Range Organics 20.0 1750 22.3 1360 112 77.9 80 130 54 - 73 130 �M 130 Toluene 20.0 22.3 ill 98.2 Xylenes,Total BO 67 1101 _ 77 130 Matrix Spike WS) / Matrix Spike Duplicate (MSD) Sample Spiked: 07030445 -01 RunID: MSDV0A2_070313A -37198 Units: ug/kg -dry Analysis Date: 03/13/2007 16 :30 Analyst: DY Preparation Date: 03/1312007 13:49 Prep By: DY Method SW5030B Analyte Sample Result Smp Qual MS Spike Added MS Result MS % Rcvry MS Qual MSD Spike Added MSD Result MSD % Rcvry MSD Qual RPD RPD Qual RPD Limit Low Limit High Limit !Benzene ND 20.6 20.2 98.2 20.6 20.8 101 2.59 - 33 41 154 Ethylbenzene ND 20.6 22.4 109 20.6 22.9 111 2.22 35 48 150 Gasoline Range Organics 17-71_ J 1800 1310 71.8 1800 1380 75.7 5.21 30 40 141 Qualifiers: ND /U - Not Detected at the Method Detection Limit MI - Matrix Interference E - Estimated Value exceeds calibration curve D - Recovery Unreportable due to Dilution J - Estimated value between MDL and PQL * - Recovery Outside Advisable QC Limits B - Analyte detected in the associated Method Blank N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply. TNTC - Too numerous to count 07030504 Page 26 QC results presented on the OC Summary Report have been rounded. RPD and percent recovery values 3/1512007 11:01:27 AM calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules. zdw�A2�� Quality Control Report ATC Associates, Inc. Vail Analysis: Volatile Organics by Method 82608 Method: SW8260B Matrix Sofke WS) / Matrix Snfke Duplicate fMSDI HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660 -0901 WorkOrder: 07030504 Lab Batch ID: 8194829 Sample Spiked: 07030445 -01 RunID: MSDVOA2_070313A•37186 Units: ug/kg -dry Analysis Date: 03/13/2007 16:30 Analyst: DY Preparation Date: 03/13/2007 13:49 Prep By: DY Method SW5030B Analyte Sample Smp MS MS MS % MS MSD MSD MSD % MSD RPD RPD RPD Law High Result Qual Spike Result Rcvry Qua[ Spike Result Rcvry Qual Qua[ Limit Limit Limit Added Added Toluene NO 20.6 21.9 _. ... - ....... 67.7 106 110 20.6 - - -- 61.8 23.0 -- -- 70.8 112 - ------- ....._ 115 4.96 4.43 _ 36 _._ 35 50 49 151 126 __ Xylenes,Total NO _ —. I 61.8 Qualifiers: ND/U - Not Detected at the Method Detection Limit MI - Matrix Interference E - Estimated Value exceeds calibration curve D - Recovery Unreportable due to Dilution J - Estimated value between MDL and PQL * - Recovery Outside Advisable QC Limits B - Analyte detected in the associated Method Blank N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply. TNTC - Too numerous to count 07030504 Page 27 QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values 31150007 11.01.27 AM calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules. zm� �� Analysis: PERCENT MOISTURE Method: D2216 Qualifiers: Quality Control Report ATC Associates, Inc. Vail Sample Duplicate HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTCN, TX 77054 (713) 660 -0901 WorkOrder: 07030504 Lab Batch ID: R194611 Samples In Analytical Batch: Lab Sample ID Client Sample ID 07030504 -01A EXC -1 -10' 07030504 -02A EXC -1 -20' 07030504 -03A EXC -1 -25' 07030504 -04A EXC -2 -10' 07030504 -05A EXC -2 -20' 07030504 -06A EXC -2 -25' Original Sample: 07030503 -01 RunID: WET_07031OD- 3714721 Units: Wt% Analysis Date: 03/10/2007 12:17 Analyst: T_L Analyte Percent Moisture Sample Result DUP Result Qua] RPD RPD Limit 2.54 2.545 0 20 ND /U - Not Detected at the Method Detection Limit MI - Matrix Interference E - Estimated Value exceeds calibration curve D - Recovery Unreportable due to Dilution J - Estimated value between MDL and PQL - Recovery Outside Advisable QC Limits B - Analyte detected in the associated Method Blank N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply. QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules. 07030504 Page 28 31152007 11:01:27 AM ZAW � Z am. Analysis: PERCENT MOISTURE Method: D2216 Quality Control Report ATC Associates, Inc. Vail HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660 -0901 W o rkOrder: 07030504 Lab Batch ID: R194612 Samples In Analytical Batch: Lab Sample ID Client Sample ID 07030504 -07A EXC -3 -10' Sample Duplicate Original Sample: 07030504 -07 RunID: WET_070310E- 3714731 Units: wt% Analysis Date: 03/1012007 12:45 Analyst: T_L Anatyte Sample Result DUP Result Quai RPD RPD Limit 20 Percent Moisture 26.2 26.2 0.0258 Qualifiers: ND /U - Not Detected at the Method Detection Limit MI - Matrix interference E - Estimated Value exceeds calibration curve D - Recovery Unreportable due to Dilution J - Estimated value between MDL and PQL Recovery Outside Advisable QC Limits B - Analyte detected in the associated Method Blank N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply. TNTC - Too numerous to count 07030504 Page 29 QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values 31161200711:01 :27 AM calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules. Sample Receipt Checklist And Chain of Custody 07030504 Page 30 3/1512007 11:01:28 Aid : Z00 Sample Receipt Checklist Workorder: 07030504 Date and Time Received: 3/10/2007 10:00:00 AM Temperature: 3.5 *C 1. Shipping containerlcooier in good condition? 2. Custody seals intact on shippping container/cooler? 3. Custody seals Intact on sample bottles? 4. Chain of custody present? 6. Chain of custody signed when relinquished and received? 6. Chain of custody agrees with sample labels? 7. Samples in proper container /bottle? 8. Sample containers Intact? 9. Sufficient sample volume for indicated test? 10. All samples received within holding time? 11, Container/Temp Blank temperature in compliance? 12. Water - VOA vials have zero headspace? 13. Water - Preservation checked upon receipt (except VOA *)? *VOA Preservation Checked After Sample Analysis HOUSTON LABORATORY 8880 INTERCHANGE DRIVE HOUSTON, TX 77054 (713) 660 -0901 Received By: Carrier name: Chilled by. RE Fedex- Priority Water Ice Yes No ❑ Not Present ❑ Yes ❑ No ❑ Not Present 0 Yes ❑ No ❑ Not Present 91 Yes No ❑ Yes ❑ No ❑ Yes No ❑ Yes No ❑ Yes No ❑ Yes ❑ No ❑ Yes No ❑ Yes 0 No ❑ Yes ❑ No ❑ VOA Vials Not Present Yes ❑ No ❑ Not Applicable SPL Representative: 1 1 Contact Date & Time: _ __ Client Name Contacted: Non Conformance Issues: Client instructions:) 07030504 Page 31 311512007 11:01:30 AM IN / �� 5PL, Inc. ® Analysis Request & Chain of Custody Record SPL Workorder No. Q s page— Client Name: G coI'lor``°j matrix O t1�� Q ri bottle ° '� Q i = a C) size 0 � o � � oo pres. O N � � M w o Z Requested Analysis � \ 1 Address: Phone/JF4x. Qa Client Contact: $ Emaili'�'�'J . Qy111't1(' Project Name/No.: Ir— Site Name: Site Location: Invoice To: Ph: SAPLE ID M DATE TFgE comp g rab E�XC.- I - kb 3 0 1 OD s G 4 Ibw 1 G-- - -20 X 515 s A- XG -1 ° 2s' 4 X30 4 G xc - -- - e 3 x 4 r 1 <� X C_— Z Client/Consultant Remarks: t , v Y �� — S � wh6� Intact? Y N Ice? -� Y ❑ N Temp, G Laboratory remarks: Requested TAT Contract ❑ 72hr ❑ Special Reportin Requirements Results: Fax ❑ Email PDF J dard QC Level 3 QC ❑ Level 4 C ❑ TX TRRP ❑ LA RECAP ❑ Special Detection Limits (specify): P1VI review (init' 1): 24hr Standard u ler dat t' a 2. Received by: 48hr ❑ Reli quis e b : date time 4. Received by: Other ❑ �. Relinquished by: d to time 6. a eiv Vbo to 8880 Interchange Drive ❑ 500 Ambassador Caffery Parkway v J 459 Hughes Drive Ho stop, TX 77054 (713) 660 -0901 Scott, LA 70583 (337) 237 -4775 Traverse City, MI 49686 (231) 947 -5777